To import (or side-load) PDF or ePub files to your NOOK for Windows 8 app:
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Swipe up from the bottom of the Home screen and select Import, or swipe right to the More section in My Library and select Import. This will display a file menu you can navigate in order to find the file to import into your library.
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Tap or click on the file to select it.
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Tap or click on the Import button to add it to your NOOK Library.
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You can view and open imported files from the My Files section of your NOOK Library.